University of Minnesota - Department of Chemical Engineering and Materials Science

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63. "The effects of ZSM-5 mesoporosity and morphology on the catalytic fast pyrolysis of furan," J. Gou, Z. Wang, C. Li, X. Qi, V. Vattipalli, Y.T. Cheng, G.W. Huber, W.C. Conner, P.J. Dauenhauer, T.J. Mountziaris, W. Fan Green Chemistry. 2017. DOI: 10.1039/c7gc01395g
62. "Biomass-Derived Butadiene by Dehydra-Decyclization of Tetrahydrofuran," Omar Abdelrahman, D.S. Park, K. Vinter, C.Spanjers, L. Ren, H.J. Cho, D.G. Vlachos, W. Fan, M. Tsapatsis, P.J. Dauenhauer, ACS Sustainable Chemistry and Engineering. 2017.
61. "Increasing Flame Ionization Detector (FID) Sensitivity using Post-Column Combustion-Methanation," Charles A. Spanjers, Connor Beach, Andrew Jones, Paul J. Dauenhauer, RSC Analytical Methods 2017, 9, 1928-1934. DOI: 10.1039/C6AY03363F
60. "Renewable Isoprene by Sequential Hydrogenation of Itaconic Acid and Dehydra-Decyclization of 3-Methyl-Tetrahydrofuran," Omar A. Abdelrahman, Dae Sung Park, Katherine P Vinter, Charles S. Spanjers, Limin Ren, Hong Je Cho, Kechun Zhang, Wei Fan, Michael Tsapatsis, Paul J. Dauenhauer, ACS Catalysis 2017, 7(2), 1428-1431. DOI: 10.1021/acscatal.6b03335
59. "Energetics of Cellulose and Cyclodextrin Glycosidic Bond Cleavage," Cheng Zhu, Christoph Krumm, Greg Facas, Matthew Neurock, Paul J. Dauenhauer Reaction Chemistry and Engineering 2017. DOI: 10.1039/C6RE00176A
58. "Production of para-methylstyrene and para-divinylbenzene from furanic compounds," Maura Koehle, Erisa Saraci, Paul Dauenhauer, Raul F. Lobo ChemSusChem 2017, 10(1), 91-98. DOI: 10.1002/cssc.201601554
57. "Tunable Oleo-Furan Surfactants by Acylation of Renewable Furans," Dae Sung Park, Kristeen E. Joesph, Maura Koehle, Christoph Krumm, Limin Ren, Jonathan N. Damen, Meera H. Shete, Han Seung Lee, Xiaobing Zuo, Byeongdu Lee, Wei Fan, Dionisios G. Vlachos, Raul F. Lobo, Michael Tsapatsis, Paul Dauenhauer, ACS Central Science 2016, 2(11), 820-824. DOI: 10.1021/acscentsci.6b00208
56. "Renewable p-Xylene from 2,5-dimethylfuran and ethylene using phosphorous-containing zeolite catalysts,," Wei Fan, Hong Je Cho, L. Ren, V. Vattipailli, Y.H. Yeh, N. Gould, B. Xu, R.J. Gorte, R. Lobo, P.J. Dauenhauer, M. Tsapatsis, ChemCatChem 2017, 9(3), 398-402. DOI: 10.1002/cctc.201601294
55. "Long Walks in Hierarchical Porous Materials due to Combined Surface and Configurational Diffusion," V. Vattipalli, X. Qi, P.J. Dauenhauer, W. Fan Chemistry of Materials 2016, 28(21), 7852-7863. DOI: 10.1021/acs.chemmater.6b03308
54. "Adsorption-Enhanced Hydrolysis of Glucan Oligomers into Glucose over Sulfonated Three-Dimensionally Ordered Mesoporous Carbon Catalysts," P. Dornath, S. Ruzycky, S. Pang, L. He, Paul Dauenhauer, Wei Fan Green Chemistry 2016, 18, 6637-6647. DOI: 10.1039/C6GC02221A
53. "Understanding Diffusion in Hierarchical Zeolites with House-of-Cards Nanosheets," P. Bai, E. Haldoupis, P.J. Dauenhauer, M. Tsapatsis, J.I. Siepmann. ACS Nano 2016, 10(8), 7612-7618. DOI: 10.1021/acsnano.6b02856
52. "Branched Diol Monomers from Sequential Hydrogenation of Renewable Carboxylic Acids," Charles S. Spanjers, Deborah K. Schneiderman, Jay Z. Wang, Jingyu Wang, Marc A. Hillmyer, Kechun Zhang, Paul J. Dauenhauer, ChemCatChem 2016, 8(19), 3031-3035. DOI: 10.1002/cctc.201600710
51. "Spontaneous Aerosol Ejection: Origin of Inorganic Particles in Biomass Pyrolysis," A.R. Teixeira, R. Gantt, K. Joseph, S. Maduskar, A.D. Paulsen, C. Krumm, C. Zhu, ChemSusChem 2016, 9(11), 1322-1328. DOI: 10.1002/cssc.201600112.
50. "Adsorption and Reaction Properties of Sn-BEA, Zr-BEA, and H-BEA for Formation of p-Xylene from DMF and Ethylene," Jingye Yu, Shiyu Zhu, Paul Dauenhauer, Hong Je Cho, Wei Fan, Raymond Gorte, Catalysis Science and Technology 2016, 6, 5729-5736. DOI: 10.1039/C6CY00501B
49. "Millisecond Pulsed Films Unify the Mechanisms of Cellulose Fragmentation," Christoph Krumm, J. Pfaendtner, P.J. Dauenhauer, Chemistry of Materials 2016, 28(9), 3108-3114. DOI: 10.1021/acs.chemmater.6b00580
48. "Micro-Ratcheted Surfaces for a Heat Engine Biomass Conveyor," Christoph Krumm, S. Maduskar, A.D. Paulsen, A. Anderson, N. Barberio, J. Damen, C. Beach, Satish Kumar, Paul Dauenhauer, Energy and Environmental Science 2016, 9, 1645-1649. DOI: 10.1039/C6EE00519E
47. "Inhibition of Xylene Isomerization in the Production of Renewable Aromatic Chemicals from Biomass-Derived Furans" C. Luke Williams, K.P. Vinter, R.E. Patet, C. Chang, N. Nikbin, S. Feng, M.R. Wiatrowski, S. Caratzoulas, W. Fan, D.G. Vlachos, P.J. Dauenhauer. ACS Catalysis. 2016, 6(3), 2076-2088.
46. "Quantitative Carbon Detector for Enhanced Detection of Molecules in Foods, Pharmaceuticals, Cosmetics, Flavors, and Fuels" Connor A. Beach, Christoph Krumm, Charles S. Spanjers, Saurabh Maduskar, Andrew J. Jones, Paul J. Dauenhauer. Analyst. 2016, 141, 1627-1632.. DOI: 10.1039/c5an02552d
45. "Alkaline Earth Metal Catalyzed Thin-Film Pyrolysis of Cellulose," Cheng Zhu, Saurabh Maduskar, Alex D. Paulsen, P.J. Dauenhauer. ChemCatChem - Chemical Catalysis and Catalytic Chemistry 2016, 8(4), 818-829. DOI: 10.1002/cctc.201501235
44. "Reply to 'Comment on the paper ''On Asymmetric Surface Barriers in MFI Zeolites Revealed by Frequency Response," Paul J. Dauenhauer, Journal of Physical Chemistry C. 2015, 119(52), 29203-29205. 10.1021/acs.jpcc.5b09512
43. "Kinetic Regimes in the Tandem Reactions of H-BEA Catalyzed Formation of p-Xylene from Dimethylfuran," C. Luke Williams, Katherine P. Vinter, Chun-Chih Chang, R. Xiong, S.K. Green, S.I. Sandler, D.G. Vlachos. W. Fan, P.J. Dauenhauer, Catalysis Science and Technology. 2016, 6, 178-187. DOI: 10.1039/C5CY01320H
42. "Lewis Acid Zeolites for Tandem Diels-Alder Cycloaddition and Dehydration of Biomass-Derived Dimethylfuran and Ethylene to Renewable p-Xylene," Chun-Chih Change, Hong Je Cho, Jingye Yu, Ray J. Gorte, Paul J. Dauenhauer, Wei Fan, Green Chemistry. 2016, 18, 1368-1376. DOI: 10.1039/C5GC02164B
41. "Diels-Alder Cycloaddition of 2-Methylfuran and Ethylene for Renewable Toluene," Sara K. Green, Ryan E. Patet, Nima Nikbin, C. Luke Williams, Chun-Chih Chang, Jingye Yu, Raymond J. Gorte, Stavros Caratzoulas, Wei Fan, Dionisios G. Vlachos, Paul J. Dauenhauer, Applied Catalysis B: Environmental, 2015, 180. 487. 10.1016/j.apcatb.2015.06.044
40. "2D Surface Structures in Small Zeolite MFI Crystals," A.R. Teixeira, X. Qi, W. Curt Conner, T.J. Mountziaris, W. Fan, P.J. Dauenhauer, Chemistry of Materials. 2015. 27(13), 4650-4660. 10.1021/acs.chemmater.5b01046
39. "Reactive Liftoff of Crystalline Cellulose Particles." A.R. Teixeira, C. Krumm, K.P. Vinter, A.D. Paulsen, C.Zhu, S. Maduskar, K.E. Joseph, K. Greco, M. Stelatto, E. Davis, B. Vincent, R. Hermann, W. Suszynski, L.D. Schmidt, W. Fan, J.P. Rothstein, P.J. Dauenhauer, Nature Scientific Reports, 2015, 5, 11238, DOI: 10.1038/srep11238.
38. "Kinetic Regime Change in the Tandem Dehydrative Aromatization of Furan Diels-Alder Products," R.E. Patet, N. Nikbin, C.L. Williams, S.K. Green, C.C. Chang, W. Fan, S. Caratzoulas, P.J. Dauenhauer, D.G. Vlachos, ACS Catalysis 2015, 5(4), 2367-2375. DOI: 10.1021/cs5020783
37. "Refuse-Derived Fuel and Integrated Calcium Hydroxide Sorbent for Coal Combustion Desulfurization," S. Chu, C. Zhu, G.A. Tompsett, T.J. Mountziaris, P.J. Dauenhauer, Industrial and Engineering Chemistry Research 2015, 54(12), 3136-3144. DOI: 10.1021/acs.iecr.5b00362
36. "Highly efficient mechano-catalytic depolymerization of crystalline cellulose by formation of branched glucan chains," P. Dornath, H.J. Cho, A.D. Paulsen, P.J. Dauenhauer, W. Fan, Green Chemistry, 2015, 15, 440-447. DOI: 10.1039/C4GC02187H
35. "Quantitative Carbon Detector (QCD) for Calibration-Free, High-Resolution Characterization of Complex Mixtures," S. Maduskar, A.R. Teixeira, A.D. Paulsen, C. Krumm, T.J. Mountziaris, W. Fan, P.J. Dauenhauer, Lab on a Chip, 2015, 15, 440-447. DOI: 10.1039/C4LC01180E. Open source by the RSC 12-month publication policy.
34. "ReEngineered Feedstocks for Pulverized Coal Combustion Emissions Control," C. Zhu, S. Chu, G. Tompsett, J. Yang, T.J. Mountziaris, P.J. Dauenhauer, Industrial and Engineering Chemistry Research. 2014,53(46), 17919-17928. DOI: 10.1021/ie502711r
33. "On Asymmetric Surface Barriers in MFI Zeolite Revealed by Frequency Response," A.R. Teixeira, X. Qi, Chun-Chih Chang, W. Fan, W.C. Conner, P.J. Dauenhauer, Journal of Physical Chemistry C, 2014 118(38), 22166-22180. DOI: 10.1021/jp507212b
32. "Solvent-Tuned Hydrophobicity of Faujasite-Catalyzed Cycloaddition of Biomass-Derived Furans for Renewable p-Xylene," R. Xiong, S.I. Sandler, D.G. Vlachos, P.J. Dauenhauer, Green Chemistry. 2014, 16, 4086. DOI: 10.1039/C4GC00727A
31. "Tuning Cellulose Pyrolysis Chemistry: Selective Decarbonylation via Catalyst-Impregnated Pyrolysis," M.S. Mettler, A.D. Paulsen, D.G. Vlachos, P.J. Dauenhauer, Catalysis Science & Technology 2014, 4, 3822-3825. DOI: 10.1039/C4CY00676C
30. "Fast Pyrolysis of Wood for Biofuels: Spatiotemporally-Resolved Diffuse Reflectance in situ Spectroscopy of Particles (STR-DRiSP)" Alex D. Paulsen, Blake, R. Hough, C. Luke Williams, Andrew R. Teixeira, Daniel T. Schwartz, J. Pfaendtner, P.J. Dauenhauer, ChemSusChem 2014, 7(3), 765-776. DOI: 10.1002/cssc.20130156
29. "Biomass at the Shale Gas Crossroads," P.J. Dauenhauer, G.W. Huber, Green Chemistry 2014, 16, 382-383.
28. "Dominance of Surface Barriers in Molecular Transport through Silicalite-1," Andrew R. Teixeira, Chun-Chih Chang, Wei Fan, Paul J. Dauenhauer, Journal of Physical Chemistry C 2013, 117(48), 25545-25555.
27. "Enhanced Molecular Transport in Hierarchical Silicalite-1," Chun-Chih chang, Andrew R. Teixeira, Chao Li, Paul J. Dauenhauer, Wei Fan, Langmuir 2013 29(45), 13943-13950.
26. "Aqueous-Phase Hydrodeoxygenation of Highly Oxygenated Aromatics on Platinum," J. Yang, C. Luke Williams, A. Ramasubramaniam, P.J. Dauenhauer, Green Chemistry 2014. 16, 675.
25. "On the Way to Biofuels from Furan: Discriminating Diels-Alder and Ring-Opening Mechanisms, "S. Vaitheeswaran, Sara Green, Paul J. Dauenhauer, Scott M. Auerbach,ACS Catalysis 2013. 3(9), 2012-2019.
24. "Ultra-Selective Cycloaddition of Dimethylfuran for Renewable p-Xylene with H-BEA," Chun-Chih Chang, Sara K. Green, C. Luke Williams, P.J. Dauenhauer, W. Fan, Green Chemistry 2014, 16, 585.
23. "Microexplosions in the upgrading of biomass-derived pyrolysis oils and the effects of simple fuel processing," A.R. Teixeira, R.J. Hermann, J.S. Kruger, W.J. Suszynski, L.D. Schmidt, D.P. Schmidt, P.J. Dauenhauer, ACS Sustainable Chemistry & Engineering 2013, 1, 341-348
22. "The Role of Sample Dimension and Temperature in Cellulose Pyrolysis," A.D. Paulsen, M.S. Mettler, P.J. Dauenhauer, Energy & Fuels 2013, 27(4), 2126-2134.
21. "A DFT study of the acid-catalyzed conversion of 2,5-dimethylfuran and ethylene to p-xylene," N. Nikbin, P.T. Do, S. Caratzoulas, R.F. Lobo, P.J. Dauenhauer, D.G. Vlachos, Journal of Catalysis 2013, 297, 35-43
20. "Ab Initio Dynamics of Cellulose Pyrolysis: Nascent Decomposition Pathways at 327 °C and 600 °C," V. Agarwal, P.J. Dauenhauer, G.W. Huber, S.M. Auerbach, Journal of the American Chemical Society (JACS) 2012, 134(36), 14958-14972.
19. "The Role of Water in the Aqueous and Vapor-Phase Adsorption of Oxygenated Aromatics on Pt and Pd," J. Yang, P.J. Dauenhauer, A. Ramasubramaniam, Journal of Computational Chemistry 2012, 34(1), 60-66.
18. "Top Ten Fundamental Challenges of Biomass Pyrolysis," M.S. Mettler, D.G. Vlachos, P.J. Dauenhauer, Energy & Environmental Science 2012, 5, 7797-7809.
17. "Cycloaddition of Biomass-Derived Furans for Catalytic Production of p-Xylene," C.Luke Williams, Chun-Chih Chang, Phuong Do, Nima Nikbin, Stavros Caratzoulas, Dionisios G. Vlachos, Raul F. Lobo, Wei Fan, Paul J. Dauenhauer, ACS Catalysis 2012, 2(6), 935-939.
16. "Pyrolytic Conversion of Cellulose to Fuels: Levoglucosan Deoxygenation via Elimination and Cyclization within Molten Biomass," M.S. Mettler, A.D. Paulsen, D.G. Vlachos, P.J. Dauenhauer, Energy & Environmental Science 2012, 5, 7864-7868.
15. "The Chain Length Effect in Pyrolysis: Bridging the Gap between Glucose and Cellulose," M.S. Metter, A.D. Paulsen, D.G. Vlachos, P.J. Dauenhauer, 2012. Green Chemistry 2012, 14, 1284-1288.
14. "Fuel for Thought" P.J. Dauenhauer,ChemSusChem 2010, 3, 386.
13. "Kinetics and reaction chemistry for slow pyrolysis of enzymatic hydrolysis lignin and organosolv extracted lignin derived from maplewood," J. Cho, S. Chu, P.J. Dauenhauer, G.W. Huber, Green Chemistry 2012, 14, 428.
12. "Revealing pyrolysis chemistry for biofuels production: Conversion of cellulose to furans and small oxygenates," M.S. Mettler, S.H. Mushrif, A.D. Paulsen, A.D. Javadekar, D.G. Vlachos, P.J. Dauenhauer, Energy and Environmental Science 2012, 5, 5414.
  Highlighted in A. Pichon, "Promising Pyrolysis," Nature Chemistry 2012, 4, 68.
11. "Aerosol Generation by Reactive Boiling Ejection of Molten Cellulose," A.R. Teixeira, K.G. Mooney, J.S. Kruger, C.L. Williams, W.J. Suszynski, L.D. Schmidt, D.P. Schmidt, P.J. Dauenhauer, Energy and Environmental Science 2011, 4, 4306.
  Highlighted in J. Yeston, "Bubbling Biomass," Science 2011, 333, 1681.
10. “Improved utilization of biomass-derived carbon by millisecond co-processing with hydrogen rich feedstocks,” J.L. Colby, P.J. Dauenhauer, A. Bhan, L.D. Schmidt, Green Chemistry 2010, 12, 378.
9. "Enhanced olefin production from renewable aliphatic feedstocks and co-fed lignin derivatives using experimental surrogates by millisecond catalytic partial oxidation," B.J. Dreyer, P.J. Dauenhauer, R. Horn, L.D. Schmidt, Ind. Eng. Chem. Res. 2010, 49, 1611.
    8. Dow Chemical Company - Internal publications (confidential)
7. “Reactive Boiling of Cellulose for Integrated Catalysis through a Liquid Intermediate” P.J. Dauenhauer, J.L. Colby, C.M. Balonek, W.J. Wieslaw, L.D. Schmidt, Green Chemistry 2009, 11, 1555.
6. “Autothermal Catalytic Partial Oxidation of Bio-oil Functional Groups: Acids and Esters,” Rennard, P.J. Dauenhauer, L.D. Schmidt, Energy & Fuels 2008, 22, 1318-1327.
5. “Millisecond Autothermal Steam Reforming of Cellulose for Synthetic Biofuels by Reactive Flash Volatilization,” J.L. Colby, P.J. Dauenhauer, L.D. Schmidt, Green Chemistry 2008, 10, 773-783.
4. “Millisecond Reforming of Solid Biomass for Sustainable Fuels,” P.J. Dauenhauer, B.J. Dreyer, N.J. Degenstein, L.D. Schmidt Angewandte Chemie, 2007, 119, 5968-5971.
  4. “Millisecond Reforming of Solid Biomass for Sustainable Fuels,” P.J. Dauenhauer, B.J. Dreyer, N.J. Degenstein, L.D. Schmidt Angewandte Chemie International Edition 2007, 46, 5864-5867.
3. "Hybrid Routes to Biofuels," L.D. Schmidt, P.J. Dauenhauer, Nature 2007, 447, 914-915.
  3. L.D. Schmidt, P.J. Dauenhauer, “Hybrid Routes to Biofuels,” Nature Reports: Climate Change 2007, 3, 44-45
2. "Renewable Hydrogen from Nonvolatile Fuels by Reactive Flash Volatilization," J.R. Salge, B.J. Dreyer, P.J. Dauenhauer, L.D. Schmidt, Science 2006, 314, 801-804.
1. "Renewable hydrogen by autothermal steam reforming of volatile carbohydrates," P.J. Dauenhauer, J.R. Salge, L.D. Schmidt, Journal of Catalysis 2006, 244, 238-247.
     
    PATENTS
  Reactive Flash Volatilization of Fluid Fuels” L.D. Schmidt, P.J. Dauenhauer, B.J. Dreyer, U.S.
Patent Pending. Application # 60/893,080
  System and Method for Volatilizing Solid Fuels to Produce Synthesis Gas” L.D. Schmidt, P.J.
Dauenhauer, B.J. Dreyer, N.J. Degenstein, U.S. Patent Pending. Application #60/893,072
  Methods of Producing Synthesis Gas using a Carbon Dioxide Feed Component” A. Bhan; L. D. Schmidt; J. C. Colby, PJ. Dauenhauer, U.S. Provisional Patent Application Serial No. 61/172,325
  Production of para-xylene by catalytically reacting 2,5-dimethylfuran and ethylene in a solvent,” P.J. Dauenhauer, C. Luke Williams, D.G. Vlachos, R.F. Lobo, C. Chang, W. Fan, U.S. Provisional Patent Application Serial No. 61/807,099.

Journal Covers

Millisecond Pulsed Films Unify the Mechanisms of Cellulose Fragmentation

Christoph Krumm, J. Pfaendtner, Paul Dauenhauer, Chemistry of Materials 2016, 28(9), 3108.

Micro-Ratcheted Surfaces for a Heat Engine Biomass Conveyor

Christoph Krumm, S. Maduskar, A.D. Paulsen, A. Anderson, N. Barberio, J. Damen, C. Beach, Satish Kumar, Paul Dauenhauer, Energy & Environmental Science 2016, DOI: 10.1039/C6EE00519E

Tuning Cellulose Pyrolysis Chemistry: Selective Decarbonylation via Catalyst-Impregnated Pyrolysis

M.S. Mettler, A.D. Paulsen, D.G. Vlachos, P.J. Dauenhauer, Catalysis Science and Technology 2014, 4, 3822-3825.

Reactive Boiling of Cellulose for Integrated Catalysis through a Liquid Intermediate

P.J. Dauenhauer, J.L. Colby, C.M. Balonek, W.J. Wieslaw, L.D. Schmidt, Green Chemistry 2009, 11, 1555.

 

Revealing pyrolysis chemistry for biofuels production: Conversion of cellulose to furans and small oxygenates

M.S. Mettler, S.H. Mushrif, A.D. Paulsen, A.D. Javadekar, D.G. Vlachos, P.J. Dauenhauer, Energy and Environmental Science 2012, 5, 5414

Fast Pyrolysis of Wood for Biofuels: Spatiotemporally-Resolved Diffuse Reflectance in situ Spectroscopy of Particles (STR-DRiSP)

Alex D. Paulsen, Blake, R. Hough, C. Luke Williams, Andrew R. Teixeira, Daniel T. Schwartz, J. Pfaendtner, P.J. Dauenhauer, ChemSusChem 2014.

 

Microexplosions in the upgrading of biomass-derived pyrolysis oils and the effects of simple fuel processing

A.R. Teixeira, R.J. Hermann, J.S. Kruger, W.J. Suszynski, L.D. Schmidt, D.P. Schmidt, P.J. Dauenhauer, ACS Sustainable Chemistry & Engineering 2013, 1, 341-348.

The Role of Water in the Aqueous and Vapor-Phase Adsorption of Oxygenated Aromatics on Pt and Pd

J. Yang, P.J. Dauenhauer, A. Ramasubramaniam, Journal of Computational Chemistry 2012, 34(1), 60-66

Highly Efficient Mechano-Catalytic Depolymerization of Crystalline Cellulose by Formation of Branched Glucan Chains

P. Dornath, H.J. Cho, A.D. Paulsen, P.J. Dauenhauer, W. Fan, Green Cheemistry 2015, 15, 440-447.

Millisecond Reforming of Solid Biomass for Sustainable Fuels

P.J. Dauenhauer, B.J. Dreyer, N.J. Degenstein, L.D. Schmidt Angewandte Chemie 2007, 119, 5968-5971.

 

 

 

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